If you were putting too much fuel into the engine there would be two possible outcomes. One is tha the engine would slober all over the place--wet stacking- and two, if there were too much fuel to late in the cycle and it would be getting down in to the engine past the rings. You would have poor power response. Too early and the engine will beat itself to death with precombustion. Could your timing gears be worn or be wobbling on one of the shafts just enough to cause it to be out of time as rpm goes up. If your timing were to far off the engine would be really run hard. You said that after the pump was replaced you started to have problems? What is she running without the cap? It is a presured system, but the water at the top of the radiator should be w/in a few degrees of that from that measured at the top of the head. 225+ is way too hot, Too hard on too many things unless you were running a synthetic oil which has a thermal breakdown of around 1500 degrees. The rubber that is used to make conventional mult-vis oil starts to break down really fast at that heat and engine pressure. Other possibilities are exhaust blow by on the valves. Have you checked compression. I would presume the head was a rebuilt/rewelded or was it from salvage but tested good. Was there a full valve job done? You have rodded the raidiator and flow checked it? There still exists the possiblity that in the last 6 years it may have finally cracked.
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