Glyphosate (Roundup), dicomba, or even Liberty/Ignite more likely these days, 24D isn't used that much any more. Anyhow around here.
Several of those products can be rainsafe in an hour, so might not be off label????
If it were a version of glyphosate only, the soap used as a sufacant is more of a problem than the actual chemical, as glyphosate binds up with clay particles _real_ quick. It would be as bad as you dumping a big box of Tide in your pond - probably not a big deal in the big picture.
I do understand your concerns, and you stated them well.
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